To illustrate the importance of annealing, I'd like to pass on something from George Kittredge.
General Dynamics did a few experiments with domes when they built the Star-1. What they found out surprised them. When testing one of the domes (that had NOT been annealed) in a chamber, it imploded at only 50 ft. So they annealed the domes and the Star-1 was able to go much deeper (I don't recall how deep)
George designed the VAST sub with a similar annealed dome (formed from 1" starting thickness) and had the sub tested in a chamber to destruction. The dome reached a depth of 823 ft! I know this was true because George showed me the test results.
So, the point is, acrylic domes after forming are full of internal stress that needs to be released. In fact, unformed acrylic sheet from the factory also has internal stress from the casting process that needs to be released. This heating process also completely polymerizes the sheet and reduces residual monomer that can caused the sheet to break down prematurely from UV exposure. Even flat viewports should be annealed for best performance.
Greg
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