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RE: [PSUBS-MAILIST] Li-ion Battery Options



Frank you took the bait and ran with it. I've been trying to see what are groups interest was in Li-ion batteries. Your idea is the first I've heard of a practical option for us to get started with Li-ion batteries.  Tesla talks allot about there Energy Storage System (ESS) and how it stops thermal runaway. I've had some ideas I worked out with an electrical tech friend of mine, for sensing the then turning off individual Li-ion batteries in a given system if they start to over heat or at least try to isolate that battery. There are also as you say safer Li-ion battery designs coming avaliable as well. It would be interesting to see how much more endurance the R300 would have using a Li-ion system.
 
Your right Frank, it's the phoshate base Li-ions that are claimed to be allot safer. The company I have been watching is the Valence company and there Saphion Technology Li-ions. Here is some data I saved in the past as well as there link.  
 
http://www.valence.com/
 
 

"Are you aware that in the United States alone over 1,600,000 lithium-ion batteries have been recalled since the year 2000?

 
 
 
The cause is not lithium-ion technology, but instead the metal-oxide based material used by most of Valence’s competitors.
 
 

The Solution is Saphion® Technology

 
For a list of recent battery recalls by leading manufacturers click here or to view the actual incident reports and the most recent recalls log onto http://www.cpsc.gov/
 
 

The Myths About Lithium-ion Battery Safety

MYTH #1: Certification Means Your Battery is Fail Safe
REALITY: Most Lithium-ion batteries sold today actually pass industry-standard certifications.  In fact, most of the battery incidents & recalls recorded involve Lithium-ion cells that were labeled as properly certified.
MYTH #2: Counterfeit batteries are the cause of many incidents
REALITY: The issue is the inherent chemistry of oxide-based lithium-ion batteries, not necessarily the manufacturing location.
MYTH #3: Mixed Oxides Make a Difference
REALITY: Any oxide technology is susceptible to thermal runaway.
MYTH #4: Safety Circuitry Prevents Events from Occurring
REALITY: Thermal runaway can occur even when internal devices and safety circuitry are present.
 

What Can Happen?

The impact of thermal runaway in an oxide-based lithium-ion battery can be disastrous. Below are two incidents which illustrate the potential danger to end users:
  • “ Curtis Sathre said it was like a bomb going off. His 13-year-old son Michael stood stunned, his ears ringing, hand gushing blood and body covered in black ash. In a split second last August, fragments from Michael's exploding cell phone had hit him between the eyes and lodged in the ceiling of the family's home in Oceanside, Calif.”

    Associated Press, Nov. 25 ‘04
     

  • “A South African teenager suffered second-degree burns on her hands and thighs after the laptop she was working on exploded.”

    Silicon.com, Jan ’03

 
 

Beyond the direct and often devastating effect to end users, manufacturers may face product liability concerns or an impact to their brand. Just imagine the magnitude of a thermal runaway event if an oxide-based lithium-ion battery were used in a large format battery application such as in mission critical back-up power or an electric fleet vehicle—the results could be catastrophic.

 

Saphion® Lithium-ion Technology:

The only safe lithium-ion technology for large format applications.

  • Safe, Phosphate-based Lithium-ion Technology (does not contain metal oxides)
     

  • Lithium-ion based performance benefits such as high energy density, lighter weight, better cycle life and no maintenance.
     

  • Plus extends traditional lithium-ion benefits with extraordinary battery longevity (beyond 2000 life cycles).
     

  • Environmentally friendly battery with no heavy metals and no need to recycle.

 

Lower Cost  •  Safe  •  Environmentally Friendly"

 

Here is some other production data I had saved.
 

"U.S. Manufacturing of Li-ion Batteries

There are many other examples of work by U.S. researchers that directly affected advanced battery systems. However, the United States has no large volume manufacturers, with only a few firms producing small volumes for specialty and military applications. U.S. companies, although global leaders in primary battery production and technology, were unable to take advantage of this early technological success. Their Southeast Asian counterparts have captured a dominant position in Li-ion battery manufacturing. Huge investments have been made in Japan, Taiwan, Korea, China, and other countries in Southeast Asia by both companies and government friendly policies for investment in competitive efforts to capture glob-al market share for rechargeable batteries for telecommunications, wireless, and computer products.
The two major U.S. battery manufacturers, Duracell and Eveready (now Energizer Holdings), began R&D efforts in Li-ion technologies around 1992, with the intent of ultimately manufacturing Li-ion batteries.
According to several senior staff interviewees, Duracell and Energizer both initiated programs for production of Li-ion batteries. In 1997, Energizer built a manufacturing facility in Gainesville, Florida outfitted with state-of-the-art equipment to produce Li-ion batteries, with production slated to start in 1999-2000. They licensed a Goodenough patent from Sony and built on their own advantaged IP positions in several areas. They had several years of experience with manufacturing Nickel Cadmium (Ni-Cd) and Ni-MH cells in Gainesville for several cellular phone and notebook computer companies. They prepared to establish a sales and marketing group in Japan to have access to the market, knowing it would take 5 years to be accepted. When the Gainesville Li-ion plant was in the "prove-in" stage, nearly ready for production, the world market price for Li-ion cells abruptly declined. The company reassessed the profitability of their investment and found it was marginal at the low cell prices. They could buy cells from Japan at a lower price than their manufacturing costs. The decision to exit Li-ion manufacture followed swiftly. The news of the low return to manufacture of Li-ion cells spread to Duracell, and they stopped their project. (Energizer sold its Gainesville facility to Moltech Corporation in 1999 after it sat idle for two years. In 2002, Moltech sold the plant to U.S. Lithium Energetics, which is seeking capital to enter production.)
Small U.S. companies and start-ups have continued to pursue innovative R&D with early-stage R&D funding from Defense Advanced Research Projects Agency (DARPA), the Advanced Technology Program, the Small Business Innovation Research program, and other federal programs. Novel Li-ion chemistries have helped carry them forward toward commercial targets. These new ventures have been most successful in niche markets (military and medical applications). New ventures have had little success in the development of significant, sizable new markets for their products. Without economies of scale, their costs of production remain high. Venture capital-funded companies tend to look off-shore for their production to mitigate the high cost of automated production equipment. Some U.S. companies with larger-scale applications have also moved offshore.
Several ATP-funded companies illustrate a spectrum of successes and failures. While large battery companies have been reluctant to enter medical markets due to liability concerns, Quallion and its joint venture partner Valtronic are develop-ing Li-ion technology to power implantable medical devices. The company is on a steep growth path. "



Regards,
Brent Hartwig



From: ShellyDalg@aol.com
Date: Mon, 31 Dec 2007 12:32:54 -0500
Subject: Re: [PSUBS-MAILIST] SubCat S-30 Data
To: personal_submersibles@psubs.org

Brent. It sure would be nice to get some of those Li-ion batteries they're using in the plug-in electric cars.
Some companies are making them the size of car batteries, and the flash recharge time to 80% is as low as 6 minutes, with a 100% charge taking 4 hours.
A car company here in Calif. called Phoenix Motorcars is producing small trucks for fleet use, and they have the batteries, but when can the general public get some ? I wonder if a group such as ours could get them to sell us some for testing in a sub ? I recall their site ( the battery co. ) as saying they promote testing their batteries in different applications.
The best one I've seen uses a nano type material, I think it was phosphate based, with virtually no danger of fire or explosion which was common on some of the other types of Li-ion batteries.
Frank D.